Some Basic Information
about Sacrificial Anodes and Boats:
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Sacrificial Anode
or “Zinc”
A sacrificial anode is an inexpensive mass
of metal, traditionally made of zinc, sometimes aluminum, which is electrically
connected to the more valuable metal components of a boat, like the propeller or
shaft. It protects these parts by “sacrificially” corroding in their place.
When two different metals are immersed in
an ELECTROLYTE (a liquid that can carry electricity) such as salt water, they
set up an electrical voltage and a current flows between them, just as in a
battery. The most “active” metal (the ANODE or positive) deteriorates by losing
positively charged metal ions into the electrolyte (corrosion) and the less
active metal (or CATHODE) is protected. This is known as GALVANIC corrosion. If
you want to protect both metals (e.g. stainless shaft and bronze propeller) you
need to connect a third metal that is more active than the first two. This is
where the term “zinc” comes in; it is one of the most active metals and is
commonly used as a sacrificial anode.
Order of Activity of Metals:

Although
zinc is the most common material, aluminum and magnesium are more active and can
provide additional protection.
The special aluminum/indium alloy used for sacrificial anodes is better
than zinc for a number of reasons:
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It
provides a bigger protection voltage (more active).
-
It “self
cleans” in freshwater. Zinc can form an oxide coating after a few months that
insulates it and makes it ineffective.
-
It has
far more current capacity for the same volume. Thus, an aluminum anode will
last 50% longer than the same anode made from zinc.
-
It is
environmentally friendly. Zinc is a “heavy metal” and causes pollution.
-
It is 1½
times lighter than zinc.
Magnesium is too active for most
boat applications. If used on a boat with a sterndrive in salt or polluted
water, the very low voltage causes the formation of hydrogen bubbles under the
paint. This results in the paint being blown off the sterndrive unit in as
little as a few hours and then very rapid corrosion of the unit. Magnesium also
has a very low capacity – only about 30% compared with zinc.
Aluminum is the ideal,
compromise anode material for all applications. It is safe in all types of water
and all types of application and provides longer and better protection than zinc
or magnesium.
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